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Essay / Primary Nds Particle Size Depending on the materials and matrices present during their manufacture, detonation NDs may contain oxides and carbides, notably those of iron, chromium, silicon, calcium, copper, potassium, titanium and sulfur, in no more carbon soot. To remove surface metal impurities, NDs are treated with conventional acid treatments containing sulfuric acid and its mixtures with nitric acid or potassium dichromate. A combination of hydrofluoric acid and nitric acid has also been used to remove metal contaminants from particles. Oxidation and subsequent removal of sp2-related carbonaceous structures, present in amorphous or graphitic form, is achieved by the use of liquid oxidants such as sodium peroxide, a mixture of chromium trioxide and sulfuric acid , or a mixture of nitric acid and hydrogen peroxide7. The thermal oxidation process uses temperatures of 400°C to 430°C to allow the oxidation of sp2-bound carbon species in air, with negligible alteration of sp3-bound carbon structures. These temperature requirements for the selective oxidation of sp2-linked carbon species were confirmed by the authors. Say no to plagiarism. Get a tailor-made essay on “Why violent video games should not be banned”? Get the original essay Oxidation of NDs at high temperatures using ozone-containing air is another approach that results in the major elimination of sp2 hybrid carbon structures. Ozone-air treatment, also known as “gas phase treatment,” is environmentally friendly and efficient because the purification of NDs is achieved without the use of corrosive liquid oxidants24. Although the size, shape, and surface properties of NDs are determined by the nature of the explosion and purification conditions, their basic structure follows a core-shell model. The carbon of the diamond forms the inert core and the surface shell partially contains graphitic structures. Additionally, a wide range of functional groups such as carboxyl, hydroxyl, lactone, anhydride, ketone, and ether can be present on the surface of these ND particles. X-ray diffraction is one of the most widely used techniques to characterize NDs, particularly in terms of size, structure and composition. When annealing the NDs at 1500 °C for 10 min in vacuum, the X-ray diffraction peak of diamond disappears with the exposure of the sp2 carbon structure peak. The crystal lattice parameters and quality of NDs can vary depending on the synthesis conditions, as determined by X-ray diffraction studies199. Keep in mind: this is just a sample. Get a personalized article from our expert writers now. Get a Custom Essay large-scale production of detonating NDs provides a significant boost to technological applications. For example, the anti-friction properties of NDs and their soot make them ideal candidates as wear protection additives. The stability of these particles at extreme temperatures had led to applications in the manufacture of composites. The large surface area of NDs is suitable for adsorption of biomolecules, presenting them as an attractive material for isolating proteins and pathogenic microorganisms, as shown in Table200.
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